3MAI1 | Solid State Electrochemistry | Materials and Chemistry | S9 | ||||||
---|---|---|---|---|---|---|---|---|---|
Lessons : 15 h | TD : 0 h | TP : 0 h | Project : 0 h | Total : 15 h | |||||
Co-ordinator : Vincent Caignaert |
Prerequisite | |
---|---|
Electrochemistry Solutions | |
Course Objectives | |
General principles of electrochemistry of solids. Some applications (sensors, electrochromism,...) Property measurements and characterization |
|
Syllabus | |
I theoretical models in electrochemistry of solids: -Load carriers: Thermodynamic models and Kinetic models -Spot defects and Brouwer's diagram -Mixed conductors in the infill phases -Mobility and transport mechanisms of load carriers: Electrochemical mobility, carrier flow, number of transport, Activated jump model, Wagner theory Application to materials carrying defects intrinséques and/or extrinséques -Ionic Conductive materials II Applications: -Electrochemical Sensors: LAMBDA probes, amperometric sensors, other gas detection sensors -Electrochemical pumps (oxygen) -Electrochemical Actuators -Electrochromisme -Electrical storage and production devices III characterization and measurement of the properties of electrochemical solids: -Impedance spectroscopy -Measurement of the number of transport -Intermittent galvanostatic titration -Intermittant Potensiostatique titration - Volta |
|
Practical work (TD or TP) | |
- Capteurs - Dispositifs lectrochromiques - Piles et batteries - Piles à combustibles - Electrosynthèse - Corrosion |
|
Acquired skills | |
Acquisition of the basic concepts of thermodynamic and kinetic models of transport in solids. Knowledge of the applications and methods of characterization of electrochemical properties. | |
Bibliography | |
Electrochimie des solides (Collection Grenoble Sciences), C. Desportes, M. Duclot, etc The CRC Handbook of Solid State Electrochemistry (Gellings & Bouwmeester) |
© 2024 - ENSICAEN ( Legal Notices - Credits )