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Applied thermodynamics

1M1AC1 Applied thermodynamics Materials and Chemistry S5
Lessons : 14 h TD : 14 h TP : 0 h Project : 0 h Total : 28 h
Co-ordinator : Jean-Pierre Gilson
Prerequisite
Non renseigné
Course Objectives
To deepen the basics of thermodynamics (state functions, chemical potential and partial molar quantities, mixing quantities..) and to be able to apply them to various physico-chemical problems: state changes, chemical reaction. We will pass from ideal systems to real systems (notions de'activité/fugacity...) by continually making the link between experimentation and thermodynamic modeling.
The concepts of metastability will be introduced in the context of phase separations and interpretation of state diagrams.
Syllabus
Introduction and reminder of the basics

Chemical potential
1) Défnition
2) Partial molar quantities
Chemical balances
4) Real-gas fugacity
5) activity of molecular solutions

Physico-Chemical balances
1) balances between pure body phases
2) liquid-vapour balances to several constituents
3) Partially miscible mixtures

Students will receive a copy of the PowerPoint presentations projected during the course
Practical work (TD or TP)
Non renseigné
Acquired skills
Ability to address problems of medium complexity and bases to deepen more advanced concepts (material surfaces, non-equilibrium thermodynamics...)
Bibliography
1. M. Chabanel & B. Illien, Thermodynamique Chimique, (2011), Ellipses, Paris
2. H-G Lee, Materials Thermodynamics, (2012), World Scientific, Londres
3. M. Scott Shell, Thermodynamics & Statistical Mechanics: An Integrated Approach, (2014), Cambridge University Press, Cambridge
4. J. Gmehling, B. Kolbe, M. Kleiber & J. Rarey, Chemical Thermodynamics for Process Simulation, (2012), Wiley-VCH, Weinheim
5.D. Kondepudi & I. Prigogine, Modern Thermodynamics: From Heat Engines to Dissipative Structures, (1998), J. Wiley & Sons, Chichester

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