1M1AC1 | Applied thermodynamics | Materials and Chemistry | S5 | ||||||
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Lessons : 14 h | TD : 14 h | TP : 0 h | Project : 0 h | Total : 28 h | |||||
Co-ordinator : Jean-Pierre Gilson |
Prerequisite | |
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Non renseigné | |
Course Objectives | |
To deepen the basics of thermodynamics (state functions, chemical potential and partial molar quantities, mixing quantities..) and to be able to apply them to various physico-chemical problems: state changes, chemical reaction. We will pass from ideal systems to real systems (notions de'activité/fugacity...) by continually making the link between experimentation and thermodynamic modeling. The concepts of metastability will be introduced in the context of phase separations and interpretation of state diagrams. |
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Syllabus | |
Introduction and reminder of the basics Chemical potential 1) Défnition 2) Partial molar quantities Chemical balances 4) Real-gas fugacity 5) activity of molecular solutions Physico-Chemical balances 1) balances between pure body phases 2) liquid-vapour balances to several constituents 3) Partially miscible mixtures Students will receive a copy of the PowerPoint presentations projected during the course |
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Practical work (TD or TP) | |
Non renseigné | |
Acquired skills | |
Ability to address problems of medium complexity and bases to deepen more advanced concepts (material surfaces, non-equilibrium thermodynamics...) | |
Bibliography | |
1. M. Chabanel & B. Illien, Thermodynamique Chimique, (2011), Ellipses, Paris 2. H-G Lee, Materials Thermodynamics, (2012), World Scientific, Londres 3. M. Scott Shell, Thermodynamics & Statistical Mechanics: An Integrated Approach, (2014), Cambridge University Press, Cambridge 4. J. Gmehling, B. Kolbe, M. Kleiber & J. Rarey, Chemical Thermodynamics for Process Simulation, (2012), Wiley-VCH, Weinheim 5.D. Kondepudi & I. Prigogine, Modern Thermodynamics: From Heat Engines to Dissipative Structures, (1998), J. Wiley & Sons, Chichester |
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